Synthesis and spectral properties of the 1‐aryl‐2‐phenyl‐4‐oxo‐4,5,6,7‐tetrahydroindole oximes and of their beckmann rearrangement products | Zendy

Dagher C. | Zendy; Hanna R. | Zendy; Terentiev P. B. | Zendy; Boundel Y. G. | Zendy; Maksimov B. I. | Zendy; Kulikov N. S. | Zendy

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Synthesis and spectral properties of the 1‐aryl‐2‐phenyl‐4‐oxo‐4,5,6,7‐tetrahydroindole oximes and of their beckmann rearrangement products

Author(s) -

Dagher C.,

Hanna R.,

Terentiev P. B.,

Boundel Y. G.,

Maksimov B. I.,

Kulikov N. S.

Publication year - 1983

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570200428

Subject(s) - chemistry , beckmann rearrangement , azepine , aryl , product (mathematics) , medicinal chemistry , oxime , stereochemistry , organic chemistry , alkyl , geometry , mathematics

Under Beckmann conditions the oximes of the 1‐aryl‐2‐phenyl‐4‐oxo‐4,5,6,7‐tetrahydroindoles 2a‐k are rearranged yielding as the sole product, 1‐aryl‐2‐phenyl‐4‐oxo‐1,4,5,6,7,8‐hexahydropyrrolo[3,2‐ c ]azepine 3a‐k . The spectral data (ir, uv, ms) of these two classes of compounds are also discussed.

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