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Benzomorphan related compounds. XVII . Oxidative cyclization of N ‐arylethyl‐6, 7‐benzomorphans
Author(s) -
Bosch Joan,
Domingo Antonio,
Granados Ricardo
Publication year - 1983
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570200409
Subject(s) - chemistry , stereochemistry , oxidative phosphorylation , medicinal chemistry , biochemistry
The synthesis of two new bridged polycyclic systems (I and II), possessing a rigid N ‐arylethylbenzomorphan structure, by mercuric acetate cyclization of the corresponding seco derivatives (IV and VI, respectively) is described. The relative configuration of these compounds and the preferred indolo[2, 3‐ a ]‐ or benzo[ a ]quin‐olizidine conformation is assigned.