Synthesis and structural analysis of a 2,5‐diazabicyclo [4.1.0]heptane | Zendy

Majchrzak Michal W. | Zendy; Kotelko Antoni | Zendy; Lambert Joseph B. | Zendy

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Synthesis and structural analysis of a 2,5‐diazabicyclo [4.1.0]heptane

Author(s) -

Majchrzak Michal W.,

Kotelko Antoni,

Lambert Joseph B.

Publication year - 1983

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570200364

Subject(s) - chemistry , heptane , bicyclic molecule , conformational isomerism , bromide , cyclopropane , salt (chemistry) , ethylene , enantiomer , ring (chemistry) , medicinal chemistry , organic chemistry , catalysis , molecule

Synthesis of a new heterocyclic system, 2, 5‐diazabicyclo [4. 1. 0] heptane, substituted on nitrogen, has been achieved by the reaction of the disodium or dipotassium salt of cis ‐1, 2‐ (arenesulfonamido) cyclopropane with ethylene bromide. Analysis of the 1 H magnetic resonance spectrum demonstrated that this bicyclic system exists as a mixture of interconverting enantiomeric half‐chair conformers.

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