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Unsymmetrically substituted furoxans. VIII . Chloromethylfuroxans
Author(s) -
Calvino R.,
Gasco A.,
Menziani E.,
Serafino A.
Publication year - 1983
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570200355
Subject(s) - chemistry , kinetics , thermal , ion , computational chemistry , medicinal chemistry , polymer chemistry , organic chemistry , thermodynamics , physics , quantum mechanics
The two isomeric chloromethylfuroxans have been prepared. Their structures, thermal equilibration and reaction toward thiophenoxide ion are discussed. Kinetics of the 4‐methyl — 3‐methyl isomer thermal conversion are also reported.