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Lack of stereoselectivity in the formation of thietane 1,1‐dioxide derivatives from anancomeric aminocyclohexenes
Author(s) -
Bradamante P.,
Forchiassin M.,
Pitacco G.,
Russo C.,
Valentin E.
Publication year - 1982
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570190502
Subject(s) - chemistry , stereoselectivity , organic chemistry , chloride , medicinal chemistry , catalysis
Two diastereoisomeric thietane 1,1‐dioxides are formed in the reaction of methanesulfonyl chloride with 4 ‐ t ‐butylcyclohexanone enamines in the presence of triethylaraine. Their structures and relative chemical stabilities are discussed.