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Chemistry of the phenoxathiins and isosterically related heterocycles. XIX. . The crystal and molecular structure of 1‐ N,N ‐dimethylamino‐2,3‐diazaphenoxathiin: An interesting product isolated from the reaction of o ‐mercaptophenol with 3,4,5‐trichloropyridazine in N,N ‐dimethylformamide
Author(s) -
Womack Charles H.,
Turley James C.,
Martin Gary E.,
Kimura Michio,
Simonsen Stanley H.
Publication year - 1981
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570180623
Subject(s) - chemistry , lone pair , nitrogen atom , crystal structure , crystallography , sulfur , product (mathematics) , group (periodic table) , nitrogen , atom (system on chip) , stereochemistry , molecule , organic chemistry , computer science , embedded system , geometry , mathematics
The isolation of 1‐ N,N ‐dimethylamino‐2,3‐diazaphenoxathiin and its molecular structure as determined by X‐ray crystallography are described. The existence of a potential non‐bonded interaction between the lone pair of electrons of the dimethylamino group nitrogen and sulfur atom are also discussed.