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An attempt to convert heterocyclic amines into azides by an aza‐transfer reaction under phase‐transfer reaction conditions
Author(s) -
Stanovnik B.,
Tišler M.,
Gabrijelčič D.,
Kunaver M.,
Žmitek J.
Publication year - 1979
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570160810
Subject(s) - chemistry , phase (matter) , transformation (genetics) , reaction conditions , combinatorial chemistry , organic chemistry , cyclic amines , amine gas treating , catalysis , biochemistry , gene
The conversion of heterocyclic amines into the corresponding azides or tetrazoloazines under phase transfer reaction conditions is described. It was found that this transformation is limited ordy to aminopyridine ( 1a‐d ) aminoisoquinoline ( 1e ) and 2‐aminobenzothiazole ( 1f ) derivatives, while other heterocyclic amines ( 1g‐w ) could not be transformed under these conditions.
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