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Markierungsexperimente zur fragmentierung von 1,2,3‐thiadiazolen
Author(s) -
Timm Uwe,
Meier Herbert
Publication year - 1979
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570160643
Subject(s) - chemistry , thiadiazoles , labelling , stereochemistry , medicinal chemistry , biochemistry
The generation of thiirenes in the thermal and photochemical nitrogen elimination of 1,2,3‐thiadiazoles is discussed in relation to oxirene formation. Isotope labelling experiments were performed with 4‐phenyl‐[4‐ 13 C]‐1,2,3‐thiadiazole ( 7 ) as the substrate.