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Stereospecific synthesis and carbon‐13 nmr spectra of 1,4‐epoxydecahydronaphthalenes
Author(s) -
Rose Charles B.,
Taylor Stephen K.
Publication year - 1979
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570160418
Subject(s) - chemistry , stereospecificity , stereoselectivity , decoupling (probability) , spectral line , nmr spectra database , carbon 13 nmr , ring (chemistry) , carbon fibers , stereochemistry , nuclear magnetic resonance spectroscopy , nuclear magnetic resonance , organic chemistry , catalysis , physics , materials science , control engineering , astronomy , composite number , engineering , composite material
The stereoselective synthesis of cis ‐fused 1,4‐epoxydecahydronaphthalenes from transannular reactions of medium‐ring compounds is described. The carbon‐13 nmr spectra of both are reported, and assignments of the various resonances have been made based on model compounds and off‐resonance decoupling experiments.