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Syntheses with α‐heterosubstituted phosphonate carbanions. VIII. An unexpected entry into quinolines
Author(s) -
Zimmer Hans,
Nene Dilip M.
Publication year - 1978
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570150734
Subject(s) - carbanion , chemistry , phosphonate , aldehyde , aryl , medicinal chemistry , organic chemistry , catalysis , alkyl
The carbanions derived of certain diphenyl‐1‐(4‐nitroanilino)‐1‐(substituted‐aryl)methanephosphonates reacted with phenylpropargyl aldehyde, giving not the expected yne‐enamines, but rather 2‐phenyl‐4‐benzyIquinolines.