1 H Nmr structural analysis of azabicyclospirohydantoins | Zendy

Trigo G. G. | Zendy; Galvez E. | Zendy; Avendaño C. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

1 H Nmr structural analysis of azabicyclospirohydantoins

Author(s) -

Trigo G. G.,

Galvez E.,

Avendaño C.

Publication year - 1978

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570150603

Subject(s) - chemistry , nonane , piperidine , ring (chemistry) , cyclohexane conformation , stereochemistry , alkyl , carbon 13 nmr , carbon atom , group (periodic table) , crystallography , molecule , organic chemistry , hydrogen bond

Based on the data from 1 H nmr spectra, the structure and spatial configuration of the ahove mentioned hydantoins are established. In the 3‐alkyl‐3‐azabicyelo[3.3.f ]nonane‐9‐spiro‐5′‐hydantoins analyzed, we confirm the chair‐chair configuration and the presence of only one stereoisomer at the spiro carbon atom (with the C 4 ′=() group axial with regard to the piperidine ring). In the 3,7‐dialkyl‐3,7‐diazabieyclo[3.3.1 ]nonane‐9‐spiro‐5′‐hydantoins analyzed, we also confirm the chair‐chair configuration and we calculate the percentage of the two stereoisomers when they exist.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research