Reactivity of 2‐amino‐1,3,4‐thiadiazoles. Nucleophilic behaviour of some 2‐amino‐1,3,4‐thiadiazoles: Model compounds | Zendy

Werber Giuseppe | Zendy; Buccheri Francesco | Zendy; Gentile Manlio | Zendy

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Reactivity of 2‐amino‐1,3,4‐thiadiazoles. Nucleophilic behaviour of some 2‐amino‐1,3,4‐thiadiazoles: Model compounds

Author(s) -

Werber Giuseppe,

Buccheri Francesco,

Gentile Manlio

Publication year - 1977

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570140727

Subject(s) - thiadiazoles , chemistry , nucleophile , acylation , reactivity (psychology) , alkylation , nitrosation , nucleophilic addition , medicinal chemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology

The ambident nucleophilic behaviour of some 2‐amino‐5‐ H ‐1,3,4‐thiadiazoles in alkylation, acylation and nitrosation reaction has been verified. The structures assigned to the 2‐amino‐1,3,4‐thiadiazoles ( 1a‐i ) and to the Δ 2 ‐1,3,4‐thiadiazolines ( 2a‐e ) agree with the spectral data.

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