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Aqueous synthesis of a new 1,3,2‐diazaphospholidine
Author(s) -
Schenkenberg Philip R.,
Williams Charles R.
Publication year - 1977
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570140625
Subject(s) - chemistry , glyoxal , aqueous solution , yield (engineering) , ring (chemistry) , organic chemistry , metallurgy , materials science
N,N,N' ‐Trimethylphosphoric triamide reacts with aqueous glyoxal to produce a 1,3,2‐diaza‐phospholidine 5‐membered ring system (III) in good yield. The ease of this synthesis belies the results with other phosphoramides where no cyclic species could be isolated.