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The configuration and solid state conformation of 3,7‐dihydroxy‐1,5‐bis( p ‐bromophenyl)octahydro‐1,5‐diazocine
Author(s) -
Peters Gary Y.,
Jensen William P.,
Worman James J.,
Jacobson Robert A.,
Nelson David A.
Publication year - 1977
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570140511
Subject(s) - chemistry , twist , crystallography , stereochemistry , crystal structure , solid state , molecule , organic chemistry , geometry , mathematics
The crystal structure of 3,7‐dihydroxy‐1,5‐bis( p ‐brornophenyl)octahydro‐1,5‐diazocine ( 4 ) has been determined from the three dimensional x‐ray diffraction data. This infers a similar structure for 3,7‐dihydroxy‐1,5‐diphenyloetahydro‐1,5‐diazocine ( 1 ). The molecules are in a twist crown conformation and the configuration of the hydroxyl groups on the 3,7‐positions is cis.