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Abnormal behavior of nitropyridines in substitution reactions with anions
Author(s) -
Kurita Keisuke,
Williams R. L.
Publication year - 1977
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570140427
Subject(s) - chemistry , substitution (logic) , isonicotinamide , medicinal chemistry , ion , substitution reaction , stereochemistry , organic chemistry , hydrogen bond , molecule , computer science , programming language
The reactions of the anions of isonicotinamide and 2‐amino‐5‐nitropyridine with 2‐chloro‐5‐nitropyridine and 3‐nitropyridine were observed to give rise to unexpected substitution products presumably via a radical anion mechanism.
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