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Oxidation of fully substituted alkoxyoxazolcs with singlet molecular oxygen
Author(s) -
Graziano M. L.,
Iesce M. R.,
Carotenulo A.,
Scarpati R.
Publication year - 1977
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570140220
Subject(s) - chemistry , singlet oxygen , photochemistry , molecular oxygen , oxygen , interpretation (philosophy) , singlet state , medicinal chemistry , organic chemistry , excited state , physics , computer science , nuclear physics , programming language
Diacylcurbamatcs IV can be prepared from alkoxyoxazoles 1 by 1 O 2 oxidation. When the reaction is opportunely earried out a new heterocyclic system, namely the 3 H ‐1, 2, 4‐dioxazole III, is formed. A mechanistic interpretation of the results is suggested.