Ion radicals. 40. Formation of 10‐phenylphenothiazine 5‐oxide and Nitro‐10‐phenylphenolhiazirie 5‐oxides by reaction of 10‐phenylphcnolhiazine cation radical perchlorate with nitrite ion | Zendy

Bandlish Baldev K. | Zendy; Kim Kyongtae | Zendy; Shine Henry J. | Zendy

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Ion radicals. 40. Formation of 10‐phenylphenothiazine 5‐oxide and Nitro‐10‐phenylphenolhiazirie 5‐oxides by reaction of 10‐phenylphcnolhiazine cation radical perchlorate with nitrite ion

Author(s) -

Bandlish Baldev K.,

Kim Kyongtae,

Shine Henry J.

Publication year - 1977

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570140208

Subject(s) - chemistry , nitration , nitrite , radical , nitrogen dioxide , inorganic chemistry , ion , nitro , oxygen , nitric oxide , oxide , nitro compound , photochemistry , nitrogen , nitrate , organic chemistry , alkyl

The reaction of 10‐phenylphenolhiazine cation radical ( 1 ) with nitrite ion leads not only to 10‐phenylphenothiazine 5‐oxide ( 2 ) but also to 3‐nitro‐10‐phenylphenothiazinc 5,5‐dioxide ( 4 ), and two dinitro‐10‐phenylphenolhia/.ine 5‐oxidcs ( 5 and 6 ). The products ( 3‐6 ) appear to he formed from the nitration of 2 by nitrogen dioxide, the nitrogen dioxide arising from the reaction of nitric oxide (formed along with 2 when 1 reacts with nitrite anion) and oxygen.

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