Premium
Synthesis of some sulfonium salts and ylides containing the isoxazole nucleus
Author(s) -
Bravo Pierfrancesco,
Gaviraghi Giovanni
Publication year - 1977
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570140107
Subject(s) - sulfonium , chemistry , isoxazole , ring (chemistry) , nucleus , organic chemistry , medicinal chemistry , salt (chemistry) , biology , microbiology and biotechnology
Some dimethylisoxazolylmethylsulfonium salts and the corresponding ylides were synthetized and their chemical behaviour studied. Dimethylsullonium‐5‐isoxazolyl methylides (XIa,b) give 5‐isoxazolyloxiranes (XIIa,d) and XIII when allowed to react with carbonyl compounds. Ring opening products from these oxiranes are also reported.