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A Novel dioxano‐annellated benzofuroxan
Author(s) -
Hadjimihalakis P. M.
Publication year - 1976
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570130637
Subject(s) - furoxan , chemistry , nitro , yield (engineering) , hypochlorite , organic chemistry , medicinal chemistry , nitric oxide , alkyl , materials science , metallurgy
Oxidation of 6‐amino‐7‐nitro‐1,4‐benzodioxane using alkaline hypochlorite affords 1,4‐benzo‐dioxano[6,7‐c]furoxan in a very good yield. Pyrolysis of 6‐azido‐7‐nitro‐1,4‐benzodioxane failed to give the same product. The structure of the new furoxan is confirmed by the spectra.