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New heterocyclic derivatives of 1′‐ and 3′‐amino‐5′,6′,7′,8′‐tetrahydro‐2′‐acetonaphthones
Author(s) -
Prieto Jose,
Vega Armando,
Moragues Jacinto
Publication year - 1976
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570130424
Subject(s) - chemistry , nitration , nitro , nitro compound , medicinal chemistry , stereochemistry , organic chemistry , combinatorial chemistry , alkyl
The preparation of 1′‐and 3′‐amino‐5′,6′,7′,8′‐tetrahydro‐2′‐acetonaphthones (IIIa and IIIb) is described, by reduction of the low temperature nitration products of 5′,6′,7′,8′‐tetrahydro‐2′‐acetonaphtone (I). The structures of the nitro isomers (IIa and IIb), and the reduction products, IIIa and IIIb, were elucidated spectroscopically. By known reactions, a series of new heterocyclic compounds prepared from the o ‐aminoketones, IIIa and IIIb, resulted in two series of new heterocyclic compounds.