Novel polycyclic heterocyeles. XIII. Derivatives of the oxime and carbinol derived from 1,2‐dihydro‐11‐(trifluoromethyl)‐3 H ,7 H ‐quino[8,1‐ cd ] [1,5]benzoxazepin‐3‐one | Zendy

Yale Harry L. | Zendy; Petigara Ramesh B. | Zendy

Premium

Novel polycyclic heterocyeles. XIII. Derivatives of the oxime and carbinol derived from 1,2‐dihydro‐11‐(trifluoromethyl)‐3 H ,7 H ‐quino[8,1‐ cd ] [1,5]benzoxazepin‐3‐one

Author(s) -

Yale Harry L.,

Petigara Ramesh B.

Publication year - 1974

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570110524

Subject(s) - chemistry , phenylisocyanate , oxime , yield (engineering) , sodium hydride , trifluoromethyl , medicinal chemistry , chloride , hydride , organic chemistry , alkyl , sodium , metal , materials science , metallurgy

The anions derived from the oxime, 2 , and the carbinol, 3 , generated by reaction with sodium hydride, were reacted with aminoalkyl chlorides and an aroyl chloride to give a number of amino‐alkyl ethers and an aroyl ester. In addition, 2 and 3 were reacted with phenylisocyanate to yield O ‐phenylcarbamoyl derivatives. The pmr spectra of several of these compounds are discussed.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research