Premium
Benzotliiazolinc derivatives. IV. Comment on the. Mechanism of reaction of 2‐l5enzolhiazolinetliione willi ethylene oxide in acetic acid
Author(s) -
Sohar Paul,
Denny George Ii.
Publication year - 1973
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570100624
Subject(s) - chemistry , acetic acid , ethylene oxide , oxide , bromide , ethylene , sodium acetate , medicinal chemistry , organic chemistry , catalysis , polymer , copolymer
Treatment of 2,3‐dihydrothiazolo|2,3‐b Iben|othiazolium bromide with sodium acetate in acetic acid gave predominantly 3‐(2‐accloxyethyl)‐2‐benothiazolinelhiorie and the minor product 3‐(2‐acetyllhioelhyl)‐2‐benzothiazolinone. The mechanistic implications of this and previous results are discussed in terms of the reaction of 2‐benzothiazolitielhione and its derivatives with ethylene oxide in acetic acid.