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The formation of a stable o ‐semidine rearrangement intermediate
Author(s) -
Paudler William W.,
Zeiler Andrew C.,
Goodman Mark M.
Publication year - 1973
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570100332
Subject(s) - chemistry , cope rearrangement , carroll rearrangement , sigmatropic reaction , stereochemistry , computational chemistry , medicinal chemistry
Treatment of 5,6,11,12‐tetrahydrodibenzo‐[ b, f ][1,2] diazocine with dilute acids affords a spiro ‐1,2,3,4‐tetrahydroquinoline derivative which represents the first isolated stable o ‐semidine rearrangement intermediate.