Premium
Selective ring opening reactions of 3,7‐diarylsulfonyl‐1,3,5,7‐tetrazabicyclo[3.3.1] nonaries
Author(s) -
Yoshida H.,
Sen C.,
Thyagarajan B. S.
Publication year - 1973
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570100301
Subject(s) - chemistry , methylene , ring (chemistry) , cleavage (geology) , methylene bridge , bridge (graph theory) , stereochemistry , combinatorial chemistry , medicinal chemistry , organic chemistry , medicine , geotechnical engineering , fracture (geology) , engineering
The selective formation of 1,3,5,7‐tetrazacyelooctanes from the title compounds is described. Exclusive cleavage of the IN‐CH 2 ‐N bonds at the bridge methylene is shown to be a facile process, thus providing a convenient route to tetrazacyclooctane derivatives.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom