Premium
The synthesis and reactions of β‐substituted ethyl sulfates
Author(s) -
Tomalia Donald A.,
Falk John Carl
Publication year - 1972
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570090424
Subject(s) - chemistry , reagent , yield (engineering) , nucleophile , carbanion , amine gas treating , ethylene , hydrolysis , organic chemistry , sulfate , ethyl iodide , catalysis , materials science , metallurgy
The synthesis of β‐substituted ethyl sulfates and their reactions with nucleophilic reagents has been studied. Amines, phenolates, carboxylates, amine oxides, carbanions, and thiophenolates reacted with ethylene sulfate in high yield, with short reaction times, and at low temperatures, to form β‐substituted ethyl sulfates. The β‐substituted ethyl sulfates were easily hydrolyzed and in some cases were converted into polymeric material.