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The mass spectra of small‐ring heterocycles. III. Aroylaziridines
Author(s) -
Cromwell Norman H.,
Woller Paul B.,
Baumgarten Henry E.,
Parker Richard G.,
Minden David L. Von
Publication year - 1972
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570090321
Subject(s) - chemistry , mass spectrum , fragmentation (computing) , fission , spectral line , ring (chemistry) , computational chemistry , simple (philosophy) , mass spectrometry , organic chemistry , nuclear physics , chromatography , physics , astronomy , philosophy , epistemology , computer science , neutron , operating system
The mass spectra of cis‐trans isomeric aroylaziridines are presented. Attempts to extend the method for distinguishing between cis and trans isomers previously established for aroylazetidines are described and the results rationalized. A simple fission of the 1‐alkylnitrogen bond is described and detailed fragmentation mechanisms are presented and discussed.