Carbenes in sulfur and nitrogen heterocycles: A π‐electron‐scf‐mo study | Zendy

Sorensen Herbert C. | Zendy; Ingraham Lloyd L. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Carbenes in sulfur and nitrogen heterocycles: A π‐electron‐scf‐mo study

Author(s) -

Sorensen Herbert C.,

Ingraham Lloyd L.

Publication year - 1971

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570080405

Subject(s) - chemistry , carbene , sulfur , computational chemistry , context (archaeology) , nitrogen , lone pair , field (mathematics) , organic chemistry , molecule , catalysis , paleontology , biology , mathematics , pure mathematics

The properties of a lone pair carbon orbital have been assessed in the context of self consistent field molecular orbital theory. An improved parameter for sulfur is presented as well as a derivation of “carbene” type parameters. The relative effects of adjacent nitrogen and/or sulfur on a carbene have been predicted and compared to experiment. Special reference has been made to the biological systems of thiamine and anhydroleucovorin.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research