Premium
Substitution and addition reactions of aziridine with perfluorinated hydrocarbons. Nuclear magnetic resonance spectra of N ‐perfluoroalkyl aziridines
Author(s) -
Lautenschlaeger F.,
Myhre M.,
Hopton F.
Publication year - 1971
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570080211
Subject(s) - chemistry , aziridine , tetracyanoethylene , chlorotrifluoroethylene , spectral line , nmr spectra database , photochemistry , organic chemistry , ring (chemistry) , medicinal chemistry , copolymer , physics , tetrafluoroethylene , astronomy , polymer
Abstract The reaction of aziridine with chlorotrifluoroethylene, perfluorobenzene, cyclic perfluoroole‐fins and tetracyanoethylene was investigated. The degree of substitution was affected by the ring size of the perfluoroolefin. The temperature dependence of the nuclear magnetic resonance spectra, particularly with respect to the temperature of coalescence of the aziridinyl protons, was investigated.