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Polarographic reduction of azines in acetonitrile
Author(s) -
Millefiori Salvatore
Publication year - 1970
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570070121
Subject(s) - polarography , chemistry , acetonitrile , reduction (mathematics) , homo/lumo , inorganic chemistry , organic chemistry , molecule , geometry , mathematics
The polarographic reduction potentials of some mono and diaza compounds were measured in acetonitrile solution and the reduction mechanism investigated by oscillopolarography and the Kouleckys analysis of the waves. Distinct regression lines were obtained for the two classes of compounds between the cathodic half‐wave potentials and the energy of the lowest unoccupied Hüekel π‐molecular orbital.
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