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The addition reaction of α‐azido ethers and α‐azido thioethers to phenylacetylene
Author(s) -
GarciaMuñoz G.,
Madroñero R.,
Rico M.,
Saldaña M. C.
Publication year - 1969
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570060624
Subject(s) - phenylacetylene , chemistry , cycloaddition , 1,3 dipolar cycloaddition , nmr spectra database , carbon 13 nmr , organic chemistry , spectral line , catalysis , physics , astronomy
Several v ‐triazoles were synthesized by 1,3‐dipolar cycloaddition of certain α‐azido ethers and α‐azidothioethers to phenylacetylene. In most of the cases the reaction led to the formation of the two isomeric v ‐triazoles. Structural assignments for the products obtained were made on the basis of NMR data and chemical reactions. Characteristic differences between the NMR spectra of the isomers have been noted.