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N ‐polyfluoroalkyl aziridines
Author(s) -
Thorn K. F.,
Sweeny N. P.,
Mcbrady J. J.
Publication year - 1969
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570060513
Subject(s) - chemistry , tetrafluoroethylene , yield (engineering) , chlorotrifluoroethylene , electrophile , ring (chemistry) , nmr spectra database , polymer chemistry , carbon 13 nmr , medicinal chemistry , spectral line , organic chemistry , catalysis , copolymer , polymer , materials science , physics , astronomy , metallurgy
Aziridines add almost quantitatively and without ring opening to tetrafluoroethylene and chlorotrifluoroethylene to yield N ‐polyfluoroalkyl aziridines. Physical properties, H 1 ‐NMR, F 19 ‐NMR and IR spectra of these compounds are reported, along with their susceptibility to undergo rearrangements catalyzed by electrophiles.