Heterocyclic  N ‐glycosides. III. Synthesis of  N ‐glycosyl‐ v ‐triazoles from glycosyl azides and phenylacetylene | Zendy

GarcíaaLóapez M. T. | Zendy; GarcíaaMun̈toz G. | Zendy; Iglesias J. | Zendy; Madroïtero R. | Zendy

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Heterocyclic N ‐glycosides. III. Synthesis of N ‐glycosyl‐ v ‐triazoles from glycosyl azides and phenylacetylene

Author(s) -

GarcíaaLóapez M. T.,

GarcíaaMun̈toz G.,

Iglesias J.,

Madroïtero R.

Publication year - 1969

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570060508

Subject(s) - phenylacetylene , chemistry , glycosyl , azide , glycosylation , glycoside , anomer , cycloaddition , stereochemistry , organic chemistry , catalysis , biochemistry

A number of v ‐triazoles were prepared by the 1,3‐dipolar cycloaddition of glycosyl azides on phenylacetylene. In all the cases studied, except when 2‐ O ‐trichloroacetyI‐3,4,6‐tri‐ O ‐acetyl‐α‐D‐glucopyranosyl azide was used, the two possible v ‐triazoles were obtained. The assignment of structure and anomeric configuration for all N ‐glycosides obtained is discussed.

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