Diazepines. VI. The chemistry of 3,8‐dihalo‐11 H ‐dibenzo[c, f ] [1,2]diazepin‐11‐ones | Zendy

Popp Frank D. | Zendy; Dubois Ronald J. | Zendy; Casey Adria Catala | Zendy

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Diazepines. VI. The chemistry of 3,8‐dihalo‐11 H ‐dibenzo[c, f ] [1,2]diazepin‐11‐ones

Author(s) -

Popp Frank D.,

Dubois Ronald J.,

Casey Adria Catala

Publication year - 1969

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.5570060303

Subject(s) - chemistry , carbonyl group , ketone , hydrazine (antidepressant) , medicinal chemistry , group (periodic table) , inert , organic chemistry , chromatography

The carbonyl group in the title compounds undergoes a number of reactions typical of ketones but in general is less reactive than a typical ketone. Reaction with hydrazine leads to reduction of the 5,6‐bond rather than reaction at the carbonyl group. Reduction of the carbonyl group gives rise to a rather inert carbinol. The carbonyl group appears to exert little influence on typical reactions at the 5,6‐position.

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