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The reactions of 2,2‐difluoro‐4‐methylnaphtho[l,2‐ e ] ‐1,3,2‐dioxaborin and Its [2,1‐ e ] Isomer with Carbonyl compounds and with Aniline
Author(s) -
Vanallan J. A.,
Reynolds G. A.
Publication year - 1969
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570060106
Subject(s) - chemistry , aniline , medicinal chemistry , organic chemistry
2,2‐Difluoro‐4‐methylnaphtho[l,2‐ e ]‐l,3,2‐dioxaborin ( 1 ) and its [2,1‐ e ]isomer ( 2 ) react with equimolecular quantities of carbonyl compounds, giving colored ethylenic derivatives. With aniline, 1 and 2 give the corresponding oxazaborins 21 and 22 . The structures of 1 and 2 are discussed.