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Stereochemistry of epimeric 1‐hydroxy‐ N ‐methylquinolizidinium iodides
Author(s) -
Temple Davis,
Sam Joseph
Publication year - 1968
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570050401
Subject(s) - chemistry , stereochemistry , nuclear magnetic resonance spectroscopy
The methiodides of epimeric 1‐hydroxy, 1‐hydroxy‐1‐phenyl, and 1‐hydroxy‐1‐methylquinolizidines were prepared from their respective bases. The previously described but not separated epimeric 1‐hydroxy‐1‐methylquinolizidines were prepared and their configurations elucidated by the use of nuclear magnetic resonance (NMR) and infrared data. Structural assignments of the quinolizidinium iodides were made on the basis of NMR data.