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Synthesis and reactions of 3,9‐diisocyanates and diisothiocyanates in the 2,4,8,10‐tetraoxa‐3,9‐diphosphaspiro[5.5] undecane series
Author(s) -
Pivawer Philip M.,
Bliss Arthur D.,
Ratz Rudi
Publication year - 1967
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570040423
Subject(s) - undecane , chemistry , phosphorus , molecule , medicinal chemistry , hydrogen atom , stereochemistry , organic chemistry , group (periodic table)
The synthesis of several novel phosphorus‐containing isocyanates and isothiocyanates is reported. These compounds are spiranes with two six‐membered dioxaphosphorinane rings in their respective molecule. The phosphorus‐bonded isocyanato and isothiocyanato groups are capable of undergoing addition reactions with active hydrogen atom‐containing compounds.