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The mass spectra of phosphorus esters. I. Bicyclic phosphites
Author(s) -
Hendricker David G.
Publication year - 1967
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570040315
Subject(s) - chemistry , bicyclic molecule , mass spectrum , fragmentation (computing) , yield (engineering) , ion , phosphorus , medicinal chemistry , hydrogen , organic chemistry , materials science , computer science , metallurgy , operating system
The mass spectra of bicyclic phosphites of the type P(OCH 2 ) 3 CR, where R = CH 3 , C 2 H 5 , and C 3 H 7 and NO 2 , are reported, and their fragmentation patterns analyzed. Unlike trialkyl phosphites, these cyclic phosphites do not yield a large number of phosphorus‐containing fragment ions resulting from hydrogen rearrangement.
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