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Reissert compound studies. XV. preparation and reaction of the reissert anion at room temperature
Author(s) -
Popp Frank D.,
Wefer John M.
Publication year - 1967
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570040204
Subject(s) - chemistry , sodium hydride , nucleophile , dimethylformamide , alkyl , sodium , medicinal chemistry , ion , hydride , organic chemistry , polymer chemistry , catalysis , hydrogen , solvent
The anions (I and II) have been conveniently generated from the parent Reissert compounds in dimethylformamide using sodium hydride. Rearrangements to ketones, alkyl‐ations, and participation of I and II in other nucleophilic displacements have been investigated.