Premium
Stereochemical studies on 7‐substituted 8‐oxa‐1‐azabicyclo[4.3.0]nonanes
Author(s) -
Crabb T. A.,
Newton R. F.
Publication year - 1966
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570030405
Subject(s) - geminal , chemistry , methylene , coupling constant , computational chemistry , stereochemistry , infrared , medicinal chemistry , quantum mechanics , physics
A set of racemic 7‐substituted 8‐oxa‐1‐azabicyclo[4.3.0]nonanes have been prepared and configurational and conformational assignments made on the basis of the value of the geminal coupling constants for the C 9 methylene protons. The limitations of the Bohlmann infrared criterion in studying the conformations of these compounds is discussed.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom