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Difluorodiazirine. II. Difluoromethane derivatives
Author(s) -
Mitsch Ronald A.
Publication year - 1964
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.5570010503
Subject(s) - difluoromethane , difluorocarbene , chemistry , yield (engineering) , chlorine , chloride , halogen , photodissociation , photochemistry , organic chemistry , medicinal chemistry , refrigerant , mechanical engineering , materials science , engineering , metallurgy , alkyl , gas compressor
The photolysis of difluorodiazirine is a convenient technique for the formation of difluorocarbene. Difluorocarbene, generated in this manner, has been shown to react with chlorine, iodine, dinitrogen tetroxide and nitryl chloride to yield the corresponding difluoromethane derivatives.