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An alternative approach to amino porphyrins
Author(s) -
Weimin Shi,
Qi Shen,
Yucheng Wang,
Lihong Lan,
Jingchao Tao
Publication year - 2010
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.410
Subject(s) - nitration , chemistry , porphyrin , tetraphenylporphyrin , yield (engineering) , nitro , organic chemistry , combinatorial chemistry , materials science , alkyl , metallurgy
Modified nitration of tetraphenylporphyrin at para of phenyl with HNO 3 /Cl 3 CCOOH and one‐pot nitration of free tetraarylporphyrins to metalized 2‐nitroporphyrin in high yield are described. A novel reducer of Zn/HCOONH 4 has been developed for above nitro of porphyrin into amino effectively. J. Heterocyclic Chem., (2010).