Premium
Carbon‐metalated triazines and tetrazines: Synthesis and reactivity
Author(s) -
Ivanov Sergey M.
Publication year - 2020
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.4071
Subject(s) - chemistry , transmetalation , electrophile , reactivity (psychology) , alkali metal , combinatorial chemistry , carbon fibers , molecule , ring (chemistry) , organic chemistry , catalysis , medicine , materials science , alternative medicine , pathology , composite number , composite material
The current review is focused on the routes for the synthesis, chemical properties and reactivity of sp 2 ‐ and sp 3 ‐carbon‐metalated triazines and tetrazines. The reported experimental data for the known compounds and intermediates including the alkali, alkaline earth, transition, and other groups 1 to 14 metal and metalloid derivatives of triazines and tetrazines were systematized. Electrophile trapping, transmetalation, couplings as well as ring opening and rearrangement reactions and their applications for the synthesis of functionalized molecules were considered.