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N ‐Hydroxy ‐1,6‐methano[10]annulene‐3,4‐dicarboximide/Co( OAc ) 2 : A novel catalytic system for the aerobic oxidation of alkylarenes
Author(s) -
Zuo Shengli,
Liu Jianjun,
Zuo Ang
Publication year - 2020
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.3971
Subject(s) - chemistry , alkylbenzenes , catalysis , annulene , cobalt , medicinal chemistry , organic chemistry
Alkylbenzenes were aerobically oxidized to their oxygenated products via a novel catalytic system using N ‐hydroxy‐1,6‐methano[10]annulene‐3,4‐dicarboximide ( 2 ) and cobalt(II) acetate under mild conditions. A radical mechanism has been proposed to account for the aerobic oxidation of these hydrocarbons. The 2 /Co(OAc) 2 catalytic system was optimized and the reaction scope was explored.