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Synthesis of Some Novel Thiadiazaphosphole, Oxazaphospholothiadiazaphosphole, Thiadiazaphosphinine, and Phosphonates Containing a 1,2,4‐Triazine Moiety
Author(s) -
Abdelkariem Somaia M.
Publication year - 2019
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.3567
Subject(s) - chemistry , moiety , reagent , triazine , phosphorus , halide , organic chemistry , sulfanyl , combinatorial chemistry , medicinal chemistry
Synthesis of some novel organophosphorus compounds bearing 1,2,4‐triazinone moiety was achieved. The methodology depended on simple reactions between 4‐amino‐6‐methyl‐3‐sulfanyl‐1,2,4‐triazin‐5(4 H )‐one ( 1 ) and variable phosphorus reagents such as phosphorus halides and phosphorus sulfides as well as phosphorous acid and its esters. These reactions were performed in proper solvents under mild conditions giving good yields of phosphorylated 1,2,4‐triazinones.