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Synthesis of 6‐Oxo‐1,2,3,4,6,7,12,12 b ‐octahydroindolo[2,3‐ a ]quinolizine
Author(s) -
Tompkins David C.,
Reilly Laurence W.,
Nelson Randall B.,
Dolby Lloyd J.,
Gribble Gordon W.
Publication year - 2018
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.3130
Subject(s) - chemistry , phenylhydrazine , alkaloid , derivative (finance) , stereochemistry , organic chemistry , financial economics , economics
An efficient synthesis of 6‐oxo‐1,2,3,4,5,7,12,12 b ‐octahydroindolo[2,3‐ α ]quinolizine from 2‐acetylpyridine and phenylhydrazine is described. This derivative of the natural alkaloid desbromoarborescidine A is an important entry point to the sarpagine‐vobasine family of plant alkaloids.

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