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Synthesis, Crystal Structure, and Properties of Energetic Complex Magnesium 5,5′‐Dinitramino‐3,3′‐bi[1,2,4‐triazolate] Hexahydrate
Author(s) -
Su Qiang,
Wang Xiao Jun,
Shu Qing Hai,
Jin Shao Hua,
Chen Shu Shen,
JieLi Li
Publication year - 2018
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.3068
Subject(s) - chemistry , magnesium , thermal decomposition , fourier transform infrared spectroscopy , elemental analysis , crystal structure , energetic material , decomposition , alkaline earth metal , metal , thermal analysis , inorganic chemistry , crystallography , thermal , chemical engineering , organic chemistry , explosive material , physics , meteorology , engineering
Alkaline Earth metal (Mg) energetic complex with 5,5′‐dinitramino‐3,3′‐bi[1,2,4‐triazolate] dihydrate (DNABT) has been synthesized and structurally characterized by FTIR spectroscopy, elemental analysis, and single X‐ray diffraction. The thermal decomposition processes of the complex and DNABT were studied by means of the TDA‐TG technologies. Sensitivity tests reveal that the complex is more insensitive to mechanical stimuli than DNABT. Combustion behavior shows that 1 has good color performances.