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Unusual Investigation of Polycyclic Saturated Tetrazine: A Breakthrough to 1,2,4,5‐Tetrazine
Author(s) -
Swain Pravat K.
Publication year - 2016
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.2376
Subject(s) - tetrazine , chemistry , diazomethane , computational chemistry , polymerization , organic chemistry , polymer
The theoretical investigation of polycyclic saturated tetrazine is a novel process, and the reaction of 1,2,4,5‐tetrazine with diazomethane that undergoes polymerization reaction has been studied by using a computational method, and it gives dinitrogen (N 2 ) as the major product. The spectroscopic studies, bond length, bond angle, heat of formation, and densities are measure of investigations in this communication. The theoretical evidence of the possibility to synthesize polycyclic saturated tetrazine is a major challenge for nitrogen‐rich chemistry.