Efficient and Eco‐friendly Syntheses of 1,5‐Benzothiazepines and 1,5‐Benzodiazepines Catalyzed by [ Hmim ][NO 3 ] under Mild Conditions | Zendy

LoghmaniKhouzani Hossein | Zendy; Tamjidi Panteha | Zendy; MohammadpoorBaltork Iraj | Zendy; Yaeghoobi Marzieh | Zendy; Rahman Noorsaadah Abd. | Zendy; Khosropour Ahmad Reza | Zendy; Moghadam Majid | Zendy; Tangestaninejad Shahram | Zendy; Mirkhani Valiolah | Zendy; Habibi Mohammad Hossein | Zendy; Kashima Ayana | Zendy; Suzuki Takayoshi | Zendy

Premium

Efficient and Eco‐friendly Syntheses of 1,5‐Benzothiazepines and 1,5‐Benzodiazepines Catalyzed by [ Hmim ][NO 3 ] under Mild Conditions

Author(s) -

LoghmaniKhouzani Hossein,

Tamjidi Panteha,

MohammadpoorBaltork Iraj,

Yaeghoobi Marzieh,

Rahman Noorsaadah Abd.,

Khosropour Ahmad Reza,

Moghadam Majid,

Tangestaninejad Shahram,

Mirkhani Valiolah,

Habibi Mohammad Hossein,

Kashima Ayana,

Suzuki Takayoshi

Publication year - 2014

Publication title -

journal of heterocyclic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.321

H-Index - 59

eISSN - 1943-5193

pISSN - 0022-152X

DOI - 10.1002/jhet.1827

Subject(s) - chemistry , diazepine , environmentally friendly , catalysis , ring (chemistry) , thiazine , combinatorial chemistry , medicinal chemistry , organic chemistry , ecology , biology

This article presents a synthetic method and reaction mechanism of the 1,5‐benzothiazepines and 1,5‐benzodiazepines derivatives. In this research, 36 thiazepines and diazepines (mostly new) with a new method have been prepared and their structures have been characterized by spectroscopic methods. Crystal structures of a new thiazepine and diazepine (seven‐membered rings) have also been determined and compared with thiazine (six‐membered ring). In this method, N ‐methylimidazolium nitrate [ Hmim ][NO 3 ] has been used as a catalyst that acts as an environmental friendly system.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research