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Dithiolopyranthione Synthesis, Spectroscopy, and an Unusual Reactivity with DDQ
Author(s) -
Pimkov Igor V.,
Nigam Archana,
Venna Kiran,
Fleming Fraser F.,
Solntsev Pavlo V.,
Nemykin Victor N.,
Basu Partha
Publication year - 2013
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.1715
Subject(s) - pyran , chemistry , reactivity (psychology) , fragmentation (computing) , bicyclic molecule , stereochemistry , spectroscopy , nuclear magnetic resonance spectroscopy , medicinal chemistry , medicine , physics , alternative medicine , pathology , quantum mechanics , computer science , operating system
The pyranodithiolone rearranges to a more stable isomer and the pyran ring opens up in the presence of DDQ.