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The Synthesis, Spectral, and Electrochemical Characterization of Novel Alkoxybenzoquinone Derivatives
Author(s) -
Ibis Cemil,
Sahinler Ayla Sibel,
Cakan Kadriye
Publication year - 2016
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.1668
Subject(s) - chemistry , acetonitrile , chloranil , cyclic voltammetry , chloroform , potassium carbonate , electrochemistry , benzoquinone , alcohol , medicinal chemistry , inorganic chemistry , organic chemistry , electrode
The novel monosubstituted benzoquinone compounds 3e , 3g , 3h ; 2,5‐ O ‐ substituted benzoquinone compounds 4a , 4b , 4c , 4d , 4e 4g and known compound 4h and 2,6‐ O ‐ substituted benzoquinone compounds 5e , 5f , 5g , 5h were obtained by the reaction of p ‐chloranil ( 1 ) and related alcohol compounds in potassium carbonate (K 2 CO 3 ) solution of acetonitrile or chloroform with Et 3 N. The novel cyclic compounds 7 , 8 and 10 , 11 were obtained from the reaction of p ‐chloranil ( 1 ) and diols in potassium carbonate (K 2 CO 3 ) solution of acetonitrile at room temperature. The structures of novel compounds were characterized by using micro analysis, FT‐IR, 1 H‐NMR, 13 C‐NMR, MS and cyclic voltammetry.